I think you mean Sqwark codes, not Selcal.
Selcall is selective Calling - Like a telephone number from a common Frequency for a specific Aircraft - Codes are Not unique worldwide but should be within each region.
Sqwark codes are transponder codes to identify an aircraft track - can show controller being worked - Scottish Mil, An Airfield etc.
Conspicuity codes can be used without specific allocation, on Takeoff etc See NATS document ENR 1.6.2