Also seen this dark line in front of aircraft many times but can only recollect it occurring on the ones either travelling roughly E to W or W to E.
I too feel it must be a shadow of the contrail created by the sun but it seems strange that, in my experience, it has only appeared as an 'extension' in front of the trail, (when the sun must have been directly behind the 'plane), and never as, for instance, a line parallel to it when the sun is abeam the plane.
Regards
Syd