Hi Jason,
As the Frequency gets higher , the Wavelength gets shorter ADSB works 1090MHz/27.5cms - microwave - which doesn't pass through much thicker than cloud, so yes 109MHz is pure line of sight, BUT you can get ducting where a signal can get "funnelled" through between the different atmospheric layers. As a matter of interest, if you watch the sunset (especially over a sea horizon) as the sun appears to touch the sea, the sun has actually set and is below the horizon out of sight, the image of the sun is ducted through the atmosphere due to light refraction, the same can happen with RF. In the mid 70s, I was caught up in the early days of CB, using illegal rigs on AM and SSB, conversations with USA and other more exotic lands were frequent due there being a "lift" on, when the signal would get bounced off one layer or another in the atmosphere. So, in summary, yes 1090MHz is line of sight, but can be reflected in certain circumstances - HTH Jon